Astonishing Alkylation and Unusual Reduction Reactions of Anionic Titanium(II) Isopropoxide Complexes: Evidence for SET Processes in Transition-Metal Oxidative Additions

2002 ◽  
Vol 2002 (12) ◽  
pp. 3091-3096 ◽  
Author(s):  
John J. Eisch ◽  
John N. Gitua
Keyword(s):  
Transition Metal ◽  
Reduction Reactions ◽  
Oxidative Additions

scholarly journals Symbiotic Transition-Metal and Organocatalysis for Catalytic Ambient Amine Oxidation and Alkene Reduction Reactions

ChemCatChem ◽  
2015 ◽  
Vol 8 (3) ◽  
pp. 510-514 ◽  
Author(s):  
Alexander T. Murray ◽  
Rose King ◽  
Joseph V. G. Donnelly ◽  
Myles J. H. Dowley ◽  
Floriana Tuna ◽  
...  
Keyword(s):  
Transition Metal ◽  
Reduction Reactions ◽  
Amine Oxidation

Kinetic and Mechanistic Aspects of Redox Reactions of Tellurium(Iv) and Tellurium(Vi)

2002 ◽  
Vol 27 (3) ◽  
pp. 127-163 ◽  
Author(s):  
K.G. Sudarsan ◽  
S.N. Dindi
Keyword(s):  
Transition Metal ◽  
Metal Ion ◽  
Redox Reactions ◽  
Mechanistic Studies ◽  
Transition Metal Ion ◽  
Reduction Reactions ◽  
Chromium Vi ◽  
Catalysed Oxidation

Many kinetic and mechanistic studies are reported on the direct and transition metal ion catalysed oxidation of tellurium(IV) with oxidants like persulphate, periodate, chromium(VI), hexacyanoferrate(III), cerium(IV), manganese(III), cobalt(III) etc. Similar studies on the reduction of tellurium(VI) by different reductants are much fewer. An attempt has been made to discuss in brief up-to-date information available on the nature of tellurium(IV) and tellurium(VI) species as well as kinetic and mechanistic studies on the direct and catalysed oxidation and reduction reactions of tellurium(IV) and tellurium(VI) respectively. The majority of reactions concerned with the oxidation of tellurium(IV) to tellurium(VI) seems to prefer a complementary path to a non-complementary one, in accordance with Schaffer's principle of equivalent change.

Transition-metal monochalcogenide nanowires: highly efficient bi-functional catalysts for the oxygen evolution/reduction reactions

Nanoscale ◽  
2020 ◽  
Vol 12 (24) ◽  
pp. 12883-12890 ◽  
Author(s):  
Wenqing Zhang ◽  
Juan Wang ◽  
Lanling Zhao ◽  
Junru Wang ◽  
Mingwen Zhao
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Low Cost ◽  
Reduction Reactions ◽  
Highly Efficient

We demonstrate the transition-metal monochalcogenide nanowires as efficient bi-functional OER/ORR catalysts competitive with noble catalysts, paving a way for the development of stable, low-cost and high-active non-noble electrocatalysts.

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